English

Macroscopic Evolution of Particle Systems with Short and Long Range Interactions

Statistical Mechanics 2009-10-31 v1

Abstract

We consider a lattice gas with general short range interactions and a Kac potential Jγ(r)J_\gamma({r}) of range γ1\gamma^{-1}, γ>0\gamma>0, evolving via particles hopping to nearest neighbor empty sites with rates which satisfy detailed balance with respect to the equilibrium measure. Scaling space like γ1\gamma^{-1} and time like γ2\gamma^{-2}, we prove that in the limit γ0\gamma \to 0 the macroscopic density profile ρ(r,t)\rho({r},t) satisfies a integro-differential equation which is in the form of the gradient flux of the energy functional F\cal F, with a mobility given by the Einstein relation Beside a regularity condition on J, the only requirement for this result is that the reference system satisfy the hypotheses of the Varadhan--Yau Theorem leading to the equation for J0J\equiv 0. Therefore the equation holds also if F\cal F achieves its minimum on non constant density profiles and this includes the cases in which {\sl phase segregation} occurs. Using the same techniques we also derive hydrodynamic equations for the densities of a two component A-B mixture with long range repulsive interactions between A and B particles. The equations for the densities ρA\rho_A and ρB\rho_B are again in the form of the gradient flux. They describe, at low temperatures, the demixing transition in which segregation takes place via vacancies, i.e. jumps to empty sites. In the limit of very few vacancies the problem becomes similar to phase segregation in a continuum system in the so called incompressible limit.

Keywords

Cite

@article{arxiv.cond-mat/0003259,
  title  = {Macroscopic Evolution of Particle Systems with Short and Long Range Interactions},
  author = {G. Giacomin and J. L. Lebowitz and R. Marra},
  journal= {arXiv preprint arXiv:cond-mat/0003259},
  year   = {2009}
}

Comments

24 pages, plain Tex, typeset twice

R2 v1 2026-07-22T10:01:15.777Z