Low-energy couplings of QCD from topological zero-mode wave functions

By matching 1/m^2 divergences in finite-volume two-point correlation functions of the scalar or pseudoscalar densities with those obtained in chiral perturbation theory, we derive a relation between the Dirac operator zero-mode eigenfunctions at fixed non-trivial topology and the low-energy constants of QCD. We investigate the feasibility of using this relation to extract the pion decay constant, by computing the zero-mode correlation functions on the lattice in the quenched approximation and comparing them with the corresponding expressions in quenched chiral perturbation theory.