English

Low-dimensional magnetism of BaCuTe$_{2}$O$_{6}$

Materials Science 2021-04-21 v2

Abstract

X-ray diffraction, thermodynamic measurements, and density-functional band-structure calculations are used to study the magnetic behavior of BaCuTe2_{2}O6_{6}, a member of the AACuTe2_2O6_6 structural family that hosts complex three-dimensional frustrated spin networks with possible spin-liquid physics. Temperature-dependent magnetic susceptibility and heat capacity of the Ba compound are well described by the one-dimensional spin-12\frac12 Heisenberg chain model reminiscent of the Sr analog SrCuTe2_2O6_6. While the intrachain coupling J/kB37J/k_{\rm B}\simeq 37 K is reduced compared to 49 K in the Sr compound, the N\'eel temperature increases from 5.5 K (Sr) to 6.1 K (Ba). Unlike the Sr compound, BaCuTe2_2O6_6 undergoes only one magnetic transition as a function of temperature and shows signatures of weak spin canting. We elucidate the microscopic difference between the Sr and Ba compounds and suggest that one of the interchain couplings changes sign as a result of negative pressure caused by the Sr/Ba substitution. The N\'eel temperature of BaCuTe2_2O6_6 is remarkably insensitive to the magnetic dilution with Zn2+^{2+} up to the highest reachable level of about 20%.

Keywords

Cite

@article{arxiv.2102.08046,
  title  = {Low-dimensional magnetism of BaCuTe$_{2}$O$_{6}$},
  author = {P. Bag and N. Ahmed and Vikram Singh and M. Sahoo and A. A. Tsirlin and R. Nath},
  journal= {arXiv preprint arXiv:2102.08046},
  year   = {2021}
}

Comments

10 pages, 11 figures, 3 tables, Accepted in Phys. Rev. B