English

Localization and freezing of a Gaussian chain in a quenched random potential

Soft Condensed Matter 2007-05-23 v1 Disordered Systems and Neural Networks

Abstract

The Gaussian chain in a quenched random potential (which is characterized by the disorder strength Δ\Delta) is investigated in the dd - dimensional space by the replicated variational method. The general expression for the free energy within so called one - step - replica symmetry breaking (1 - RSB) scenario has been systematically derived. We have shown that the replica symmetrical (RS) limit of this expression can describe the chain center of mass localization and collapse. The critical disorder when the chain becomes localized scales as ΔcbdN2+d/2\Delta_c \simeq b^d N^{-2 + d/2} (where bb is the length of the Kuhn segment length and NN is the chain length) whereas the chain gyration radius Rgb(bd/Δ)1/(4d)R_{\rm g} \simeq b (b^d/\Delta)^{1/(4 - d)}. The freezing of the internal degrees of freedom follows to the 1-RSB - scenario and is characterized by the beads localization length D2ˉ\bar{{\cal D}^2}. It was demonstrated that the solution for D2ˉ\bar{{\cal D}^2} appears as a metastable state at Δ=ΔA\Delta = \Delta_A and behaves similarly to the corresponding frozen states in heteropolymers or in pp - spin random spherical model.

Keywords

Cite

@article{arxiv.cond-mat/0312435,
  title  = {Localization and freezing of a Gaussian chain in a quenched random potential},
  author = {Vakhtang G. Rostiashvili and Thomas A. Vilgis},
  journal= {arXiv preprint arXiv:cond-mat/0312435},
  year   = {2007}
}

Comments

18 pages, 6 figures, submitted to J. Chem. Phys