English

Lifshitz interaction can promote ice growth at water-silica interfaces

Other Condensed Matter 2017-12-04 v1 Soft Condensed Matter

Abstract

At air-water interfaces, the Lifshitz interaction by itself does not promote ice growth. On the contrary, we find that the Lifshitz force promotes the growth of an ice film, up to 1-8 nm thickness, near silica-water interfaces at the triple point of water. This is achieved in a system where the combined effect of the retardation and the zero frequency mode influences the short-range interactions at low temperatures, contrary to common understanding. Cancellation between the positive and negative contributions in the Lifshitz spectral function is reversed in silica with high porosity. Our results provide a model for how water freezes on glass and other surfaces.

Keywords

Cite

@article{arxiv.1704.01332,
  title  = {Lifshitz interaction can promote ice growth at water-silica interfaces},
  author = {Mathias Boström and Oleksandr I. Malyi and Prachi Parashar and K. V. Shajesh and Priyadarshini Thiyam and Kimball A. Milton and Clas Persson and Drew F. Parsons and Iver Brevik},
  journal= {arXiv preprint arXiv:1704.01332},
  year   = {2017}
}

Comments

Accepted for publication in Physical Review B