English

Lifetime of dynamical heterogeneity in a highly supercooled liquid

Soft Condensed Matter 2012-04-25 v3

Abstract

We numerically examine dynamical heterogeneity in a highly supercooled three-dimensional liquid via molecular-dynamics simulations. To define the local dynamics, we consider two time intervals, τα\tau_\alpha and τngp\tau_{\text{ngp}}. τα\tau_\alpha is the α\alpha relaxation time, and τngp\tau_{\text{ngp}} is the time at which non-Gaussian parameter of the van Hove self-correlation function is maximized. We determine the lifetimes of the heterogeneous dynamics in these two different time intervals, τhetero(τα)\tau_{\text{hetero}}(\tau_\alpha) and τhetero(τngp)\tau_{\text{hetero}}(\tau_{\text{ngp}}), by calculating the time correlation function of the particle dynamics, i.e., the four-point correlation function. We find that the difference between τhetero(τα)\tau_{\text{hetero}}(\tau_\alpha) and τhetero(τngp)\tau_{\text{hetero}}(\tau_{\text{ngp}}) increases with decreasing temperature. At low temperatures, τhetero(τα)\tau_{\text{hetero}}(\tau_\alpha) is considerably larger than τα\tau_{\alpha}, while τhetero(τngp)\tau_{\text{hetero}}(\tau_{\text{ngp}}) remains comparable to τα\tau_{\alpha}. Thus, the lifetime of the heterogeneous dynamics depends strongly on the time interval.

Keywords

Cite

@article{arxiv.1006.3704,
  title  = {Lifetime of dynamical heterogeneity in a highly supercooled liquid},
  author = {Hideyuki Mizuno and Ryoichi Yamamoto},
  journal= {arXiv preprint arXiv:1006.3704},
  year   = {2012}
}

Comments

4pages, 6figures