English

Legendre transforms for electrostatic energies

Statistical Mechanics 2012-11-29 v1

Abstract

We review the use of Legendre transforms in the formulation of electrostatic energies in condensed matter. We show how to render standard functionals expressed in terms of the electrostatic potential, Phi, convex - at the cost of expressing them in terms of the vector field D. This leads to great simplification in the formulation of numerical minimisation of electrostatic energies coupled to other physical degrees of freedom. We also demonstrate the equivalence of recent functionals for dielectrics derived using field theory methods to classical formulations in terms of the electric polarisation.

Cite

@article{arxiv.1211.6601,
  title  = {Legendre transforms for electrostatic energies},
  author = {Justine S. Pujos and A. C. Maggs},
  journal= {arXiv preprint arXiv:1211.6601},
  year   = {2012}
}

Comments

7 pages; CECAM workshop: New Challenges in Electrostatics of Soft and Disordered Matter (May 7, 2012 to May 10, 2012): http://www.cecam.org/workshop-0-689.html

R2 v1 2026-06-21T22:45:27.262Z