English

Isotope effect in superconducting lanthanum hydride under high compression

Superconductivity 2020-06-03 v2

Abstract

Recently, the discovery of room-temperature superconductivity (SC) was experimentally realized in the fcc phase of LaH10_{10} under megabar pressure. Specifically, the isotope effect of TcT_{\rm c} was measured by the replacement of hydrogen (H) with deuterium (D), demonstrating a driving role of phonons in the observed room-temperature SC. Herein, based on the first-principles calculations within the harmonic approximation, we reveal that (i) the identical electron-phonon coupling constants of fcc LaH10_{10} and LaD10_{10} decrease monotonously with increasing pressure and (ii) the isotope effect of TcT_{\rm c} is nearly proportional to MαM^{-{\alpha}} (MM: ionic mass) with α{\alpha} {\approx} 0.465, irrespective of pressure. The predicted value of α{\alpha} agrees well with the experimental one (α=0.46{\alpha}=0.46) measured at around 150 GPa. Thus, our findings provide a theoretical confirmation of the conventional electron-phonon coupling mechanism in a newly discovered room-temperature superconductor of compressed LaH10_{10}.

Keywords

Cite

@article{arxiv.1912.09663,
  title  = {Isotope effect in superconducting lanthanum hydride under high compression},
  author = {Artur P. Durajski and Radoslaw Szczesniak and Yinwei Li and Chongze Wang and Jun-Hyung Cho},
  journal= {arXiv preprint arXiv:1912.09663},
  year   = {2020}
}

Comments

7 pages, 5 figures

R2 v1 2026-06-23T12:52:02.657Z