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Is Li$_2$Pd$_3$B a self-doped hole superconductor ?

Superconductivity 2009-11-10 v2 Strongly Correlated Electrons

Abstract

We propose that the electrons responsible for superconductivity in Li2Pd3B come from the palladium 4d-electrons. So, its electronic properties are likely to be dominated by strong electronic correlations. The basic unit in this material are Pd6_6B octahedra which share vertices to form a 3-dimensional network. Due to the highly distorted nature of the Pd6_6B octahedron, one far stretched Pd atom per octahedra becomes almost inactive for electronic conduction. Thus, the material escapes the fate of becoming a half- filled insulating Mott antiferromagnet by hiding extra charges at these inactive Pd sites and becomes a self-doped correlated metal. We propose a 3-dimensional single band t-J model which could be the correct minimal model for this material.

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Cite

@article{arxiv.cond-mat/0404168,
  title  = {Is Li$_2$Pd$_3$B a self-doped hole superconductor ?},
  author = {Manas Sardar and Debanand Sa},
  journal= {arXiv preprint arXiv:cond-mat/0404168},
  year   = {2009}
}

Comments

4 pages Revtex, 2 figures included in the text, some typos corrected, some text and references added