English

Investigation on non-ergodicity of protein dynamics

Soft Condensed Matter 2025-01-16 v1 Biological Physics Biomolecules

Abstract

The study of microscopic protein dynamics has historically presented significant challenges to researchers seeking to develop a comprehensive and detailed description of its diverse and intriguing features. Recent experimental and theoretical studies have proposed the hypothesis that protein dynamics may be non-ergodic. The implications of this finding are of paramount importance from both a practical and theoretical standpoint. In this study, we employ all-atom molecular dynamics simulations to examine these results over a time window spanning from picoseconds to nanoseconds. To this end, we utilize widely used statistical tools. Our findings challenge the conclusions of previous studies, which suggested that proteins exhibit non-ergodic dynamics. Instead, we demonstrate that deviations from ergodic behavior are due to incomplete convergence of the investigated quantities. Additionally, we discuss the implications of findings that suggest a potential breaking of the ergodic hypothesis over larger time windows, which were not directly investigated in this study.

Keywords

Cite

@article{arxiv.2501.08754,
  title  = {Investigation on non-ergodicity of protein dynamics},
  author = {Luca Maggi},
  journal= {arXiv preprint arXiv:2501.08754},
  year   = {2025}
}