A fundamental issue at the core of trajectory optimization on smooth manifolds is handling the implicit manifold constraint within the dynamics. The conventional approach is to enforce the dynamic model as a constraint. However, we show this approach leads to significantly redundant operations, as well as being heavily dependent on the state space representation. Specifically, we propose an intrinsic successive convexification methodology for optimal control on smooth manifolds. This so-called iSCvx is then applied to a representative example involving attitude trajectory optimization for a spacecraft subject to non-convex constraints.