Interplay between magnetic properties and thermoelectricity in misfit and Na cobaltates

J. Bobroff; S. Hebert; G. Lang; P. Mendels; D. Pelloquin; A. Maignan

doi:10.1103/PhysRevB.76.100407

Interplay between magnetic properties and thermoelectricity in misfit and Na cobaltates

Strongly Correlated Electrons 2009-11-13 v2 Materials Science

Authors: J. Bobroff , S. Hebert , G. Lang , P. Mendels , D. Pelloquin , A. Maignan

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Abstract

We present a comparative study of CoO2 layers in the Bi-misfit and NaxCoO2 cobaltates. Co NMR measures the intrinsic susceptibility of the Co layers and is not affected by spurious contributions. At low dopings where room-temperature thermopower (TEP) is large, Curie-Weiss susceptibilities are observed in both materials. But NMR and muSR experiments find neither charge nor spin order down to low temperatures in Bi-misfit, in contrast to the case of NaxCoO2. This demonstrates that metallicity, charge and magnetic orders are specific of the Na layers in NaxCoO2 whereas strong correlations are generic of the cobaltates physics and could explain the large TEP.

Keywords

cobaltates thermoelectricity magnetic properties Co NMR muSR charge order spin order strong correlations

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@article{arxiv.0704.3512,
  title  = {Interplay between magnetic properties and thermoelectricity in misfit and Na cobaltates},
  author = {J. Bobroff and S. Hebert and G. Lang and P. Mendels and D. Pelloquin and A. Maignan},
  journal= {arXiv preprint arXiv:0704.3512},
  year   = {2009}
}

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4 pages

Interplay between magnetic properties and thermoelectricity in misfit and Na cobaltates

Abstract

Keywords

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