English

Internal Structure and CO$_2$ Reservoirs of Habitable Water-Worlds

Earth and Planetary Astrophysics 2020-02-26 v1

Abstract

Water-worlds are water-rich (>1 wt% H2_2O) exoplanets. The classical models of water-worlds considered layered structures determined by the phase boundaries of pure water. However, water-worlds are likely to possess comet-like compositions, with between ~3 mol% to 30 mol% CO2_2 relative to water. In this study, we build an interior structure model of habitable (i.e. surface-liquid-ocean-bearing) water-worlds using the latest results from experimental data on the CO2_2-H2_2O system, to explore the CO2_2 budget and to localize the main CO2_2 reservoirs inside of these planets. We show that CO2_2 dissolved in the ocean and trapped inside of a clathrate layer cannot accommodate a cometary amount of CO2_2 if the planet accretes more than 11 wt% of volatiles (CO2_2 + H2_2O) during its formation. We propose a new, potentially dominant, CO2_2 reservoir for water-worlds: CO2_2 buried inside of the high-pressure water ice mantle as CO2_2 ices or (H2_2CO3_3 . H2_2O), monohydrate of carbonic acid. If insufficient amounts of CO2_2 are sequestered either in this reservoir or the planet's iron core, habitable zone water-worlds could generically be stalled in their cooling before liquid oceans have a chance to condense.

Keywords

Cite

@article{arxiv.1904.10458,
  title  = {Internal Structure and CO$_2$ Reservoirs of Habitable Water-Worlds},
  author = {Nadejda Marounina and Leslie A. Rogers},
  journal= {arXiv preprint arXiv:1904.10458},
  year   = {2020}
}

Comments

Submitted to ApJ October 1st, 2018