The paper presents the first-principle calculation of the electron-phonon coupling and the temperature dependence of the intrinsic electrical resistivity of the zirconium-hydrogen system with various hydrogen concentrations. The nature of the anomalous decrease in the electrical resistivity of the Zr-H system with the increase of hydrogen concentration (at the high concentrations of H/Zr>1.5) was studied. It was found that the hydrogen concentration, where the resistivity starts to decrease, is very close to the critical concentration of the δ−ε phase transition. It was shown that the tetragonal lattice distortion due to the δ−ε phase transition of the Zr-H system eliminates imaginary phonon frequencies and the strong electron-phonon coupling of the δ phase and, as a result, leads to the reduction of the electrical resistivity of the Zr-H system at a high hydrogen concentration.
@article{arxiv.1806.00847,
title = {Influence of hydrogen on electron-phonon coupling and intrinsic electrical resistivity in zirconium: a first-principles study},
author = {Qicheng Tang and L. A. Svyatkin and I. P. Chernov},
journal= {arXiv preprint arXiv:1806.00847},
year = {2019}
}