English

Identification of the Polaron measure in strong coupling and the Pekar variational formula

Probability 2021-07-27 v3

Abstract

The path measure corresponding to the Fr\"ohlich Polaron appearing in quantum statistical mechanics is defined as the tilted measure P^ε,T=1Z(ε,T)exp(12TTTTεeεtsω(t)ω(s)dsdt)dP. \widehat{\mathbb P}_{\varepsilon,T}= \frac{1}{Z(\varepsilon,T)}\exp\bigg(\frac{1}{2}\int_{-T}^T\int_{-T}^T \frac{\varepsilon\mathrm e^{-\varepsilon |t-s|}}{|\omega(t)-\omega(s)|} \mathrm d s \,\mathrm d t\bigg)\mathrm d\mathbb P. Here ε>0\varepsilon>0 is the Kac parameter (or the inverse-coupling), and P\mathbb P is the law of 3d3d Brownian increments. In [13] it was shown that the (thermodynamic) limit limTP^ε,T=P^ε\lim_{T\to\infty}\widehat{\mathbb P}_{\varepsilon,T}=\widehat{\mathbb P}_\varepsilon exists as a process with stationary increments and this limit was identified explicitly as a mixture of Gaussian processes. In the present article, the strong coupling limit or the vanishing Kac parameter limit limε0P^ε\lim_{\varepsilon\to 0} \widehat{\mathbb P}_\varepsilon is investigated. It is shown that this limit exists and coincides with the increments of the Pekar process, which is a stationary diffusion process with generator 12Δ+(ψ/ψ)\frac 12 \Delta+ (\nabla\psi/\psi)\cdot \nabla, where ψ\psi is the unique (modulo shifts) maximizer of the Pekar variational problem g0=supψ2=1{R3R3ψ2(x)ψ2(y)xy1dxdy12ψ22}. g_0=\sup_{\|\psi\|_2=1} \Big\{\int_{\mathbb R^3}\int_{\mathbb R^3}\,\psi^2(x) \psi^2(y)|x-y|^{-1}\mathrm d x\mathrm d y -\frac 12\|\nabla \psi\|_2^2\Big\}. As shown in [12,6,1], the Pekar process is itself approximated by the limiting "mean-field Polaron measures", and thus, the present identification of the strong coupling Polaron is a rigorous justification of the "mean-field approximation" (on the level of path measures) conjectured by Spohn in [15]. This approximation in the vanishing Kac limit (ε0\varepsilon\to 0) is also shown to hold for a general class of Kac-Interaction of the form H(t,x)=εeεtV(x)H(t,x)=\varepsilon \mathrm e^{-\varepsilon|t|} V(x) where VV is any continuous function vanishing at infinity.

Keywords

Cite

@article{arxiv.1812.06927,
  title  = {Identification of the Polaron measure in strong coupling and the Pekar variational formula},
  author = {Chiranjib Mukherjee and S. R. S. Varadhan},
  journal= {arXiv preprint arXiv:1812.06927},
  year   = {2021}
}

Comments

To appear in "Annals of Probability"