Using the molecular dynamics simulations we investigate properties of velocity autocorrelation function of Lennard-Jones fluid at long and intermediate time scales in wide ranges of temperature and density. We show that the amplitudes of the leading and subleading VAF time asymptotes, a1 and a2, show essentially non monotonous temperature and density dependence. There are two lines on temperature-density plain corresponding to maxima of a1 (a2) along isochors and isotherms situated in the supercritical fluid (hydrodynamic anomalies). These lines give insight into the stages of the fluid evolution into gas.
@article{arxiv.1407.5462,
title = {Hydrodynamic anomalies in supercritical fluid},
author = {R. E. Ryltsev and N. M. Chtchelkatchev},
journal= {arXiv preprint arXiv:1407.5462},
year = {2014}
}