English

Hydrodynamic anomalies in supercritical fluid

Soft Condensed Matter 2014-09-30 v2 Statistical Mechanics

Abstract

Using the molecular dynamics simulations we investigate properties of velocity autocorrelation function of Lennard-Jones fluid at long and intermediate time scales in wide ranges of temperature and density. We show that the amplitudes of the leading and subleading VAF time asymptotes, a1a_1 and a2a_2, show essentially non monotonous temperature and density dependence. There are two lines on temperature-density plain corresponding to maxima of a1a_1 (a2a_2) along isochors and isotherms situated in the supercritical fluid (hydrodynamic anomalies). These lines give insight into the stages of the fluid evolution into gas.

Keywords

Cite

@article{arxiv.1407.5462,
  title  = {Hydrodynamic anomalies in supercritical fluid},
  author = {R. E. Ryltsev and N. M. Chtchelkatchev},
  journal= {arXiv preprint arXiv:1407.5462},
  year   = {2014}
}
R2 v1 2026-06-22T05:08:47.452Z