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How the Hahn-Banach Theorem Sheds Bright Light on Fundamental Questions in Classical Thermodynamics

Classical Physics 2026-05-12 v2 Mathematical Physics Dynamical Systems Functional Analysis math.MP Chemical Physics

Abstract

The Hahn-Banach Theorem, a cornerstone of modern functional analysis, is a natural companion of the Second Law of Thermodynamics. From a Kelvin-Planck version of the Second Law, the Hahn-Banach Theorem delivers, immediately and simultaneously, entropy and thermodynamic-temperature functions of the local material state such that the Clausius-Duhem inequality is satisfied for every process a particular material might admit. For \emph{existence} of such functions there is no need at all to require that their domain be restricted to states of equilibrium. However, the Hahn-Banach Theorem also indicates that for \emph{uniqueness} of such a pair of functions across the entire state-space domain, every state must be visited by a reversible process. This review is intended to help make accessible to both thermodynamics scholars and mathematicians the remarkable interplay of the Hahn-Banach Theorem and the Second Law.

Keywords

Cite

@article{arxiv.2604.22717,
  title  = {How the Hahn-Banach Theorem Sheds Bright Light on Fundamental Questions in Classical Thermodynamics},
  author = {Martin Feinberg and Richard B. Lavine},
  journal= {arXiv preprint arXiv:2604.22717},
  year   = {2026}
}