English

How Are Quantum Eigenfunctions of Hydrogen Atom Related To Its Classical Elliptic Orbits?

Quantum Physics 2026-05-13 v2 Atomic Physics

Abstract

We show that a highly-excited energy eigenfunction ψnlm(r)\psi_{nlm}(\vec{r}) of hydrogen atom can be approximated as an equal-weight superposition of classical elliptic orbits with energy EnE_n and angular momentum L=l(l+1)L=\sqrt{l(l+1)}\hbar, and zz component of angular momentum Lz=mL_z=m\hbar. This correspondence is established by comparing the quantum probability distribution ψnlm(r)2|\psi_{nlm}(\vec{r})|^2 and the classical probability distribution pc(r)p_c(\vec{r}) of an ensemble of such orbits. This finding illustrates a general principle: in the semi-classical limit, an energy eigenstate of a quantum system is in general reduced to a collection of classical orbits, rather than a single classical orbit.

Keywords

Cite

@article{arxiv.2411.18890,
  title  = {How Are Quantum Eigenfunctions of Hydrogen Atom Related To Its Classical Elliptic Orbits?},
  author = {Yixuan Yin and Tiantian Wang and Biao Wu},
  journal= {arXiv preprint arXiv:2411.18890},
  year   = {2026}
}