English

High magnetic anisotropy and magnetocaloric effects in single crystal Cr$_2$Te$_3$

Materials Science 2023-12-05 v1

Abstract

We report a systematic investigation of anisotropic magnetocaloric effects in single crystal Cr2_2Te3_3. Single crystal samples are synthesized by chemical vapor transport and characterized by x-ray and Laue diffraction methods. The maximum magnetic entropy change ΔSMmax-\Delta S_{\text M}^{\text{max}} is 4.50 J kg1^{-1} K1^{-1} for the easy c-axis (3.36 J kg1^{-1} K1^{-1} for the hard ab-plane) and the relative cooling power RCP is 296.7 J kg1^{-1} for the easy c-axis (183.84 J kg1^{-1} for the hard axis ab-plane) near the Curie temperature for a magnetic field change of 9 T. The magneto-crystalline anisotropy constant Ku_u is estimated to be 486.92 kJ m3^{-3} at 146 K, decreasing to 148.60 kJ m3^{-3} at 168 K. Meanwhile, the maximum of the rotational magnetic entropy change ΔSMR(T,H)\Delta S_{\text M}^{\text R}(T, H) between the c-axis and the ab-plane is about 1.14 J kg1^{-1}K1^{-1} for magnetic-field change of 9 T. The critical exponents are estimated by analyzing magnetocaloric effects, which indicate 2D-Ising type magnetic system. The accuracy of estimated critical exponents is verified by scaling analysis. The maximum magnetic entropy change ΔSMmax-\Delta S_{\text M}^{\text{max}} \approx5.25 J kg1^{-1} K1^{-1} (along the c-axis) and the corresponding adiabatic temperature change ΔTad\Delta T_{\text{ad}} \approx3.31 K (along the c-axis) are estimated by analyzing heat capacity measurements with a magnetic field up to 9 Tesla.

Keywords

Cite

@article{arxiv.2312.01000,
  title  = {High magnetic anisotropy and magnetocaloric effects in single crystal Cr$_2$Te$_3$},
  author = {Anirban Goswami and Nicholas Ng and AM Milinda Abeykoon and Emmanuel Yakubu and Samaresh Guchhait},
  journal= {arXiv preprint arXiv:2312.01000},
  year   = {2023}
}