We report a systematic investigation of anisotropic magnetocaloric effects in single crystal Cr2Te3. Single crystal samples are synthesized by chemical vapor transport and characterized by x-ray and Laue diffraction methods. The maximum magnetic entropy change −ΔSMmax is 4.50 J kg−1 K−1 for the easy c-axis (3.36 J kg−1 K−1 for the hard ab-plane) and the relative cooling power RCP is 296.7 J kg−1 for the easy c-axis (183.84 J kg−1 for the hard axis ab-plane) near the Curie temperature for a magnetic field change of 9 T. The magneto-crystalline anisotropy constant Ku is estimated to be 486.92 kJ m−3 at 146 K, decreasing to 148.60 kJ m−3 at 168 K. Meanwhile, the maximum of the rotational magnetic entropy change ΔSMR(T,H) between the c-axis and the ab-plane is about 1.14 J kg−1K−1 for magnetic-field change of 9 T. The critical exponents are estimated by analyzing magnetocaloric effects, which indicate 2D-Ising type magnetic system. The accuracy of estimated critical exponents is verified by scaling analysis. The maximum magnetic entropy change −ΔSMmax≈5.25 J kg−1 K−1 (along the c-axis) and the corresponding adiabatic temperature change ΔTad≈3.31 K (along the c-axis) are estimated by analyzing heat capacity measurements with a magnetic field up to 9 Tesla.
@article{arxiv.2312.01000,
title = {High magnetic anisotropy and magnetocaloric effects in single crystal Cr$_2$Te$_3$},
author = {Anirban Goswami and Nicholas Ng and AM Milinda Abeykoon and Emmanuel Yakubu and Samaresh Guchhait},
journal= {arXiv preprint arXiv:2312.01000},
year = {2023}
}