All previous cuprate superconductors display a set of common features: (i) vicinity to a Cu 3d9 configuration; (ii) separated CuO2 planes; (iii) superconductivity for doping δ∼ 0.1−0.3. Recently [PNAS {\bf 24}, 12156 (2019)] challenged this picture by discovering "highly overdoped" superconducting Ba2CuO3+y. Using density-functional theory + dynamical mean-field theory, we reveal a bilayer structure of Ba2CuO3.2 of alternating quasi 2D and quasi 1D character. Correlations tune an inter-layer self-doping leading to an almost half-filled, strongly nested quasi 1D db2−c2 band, which is prone to strong antiferromagnetic fluctuations, possibly at the origin of superconductivity in Ba2CuO3+y.
@article{arxiv.2107.11897,
title = {Hidden, one-dimensional, strongly nested, and almost half-filled Fermi surface in Ba$_2$CuO$_{3+y}$ superconductors},
author = {Paul Worm and Motoharu Kitatani and Jan M. Tomczak and Liang Si and Karsten Held},
journal= {arXiv preprint arXiv:2107.11897},
year = {2022}
}