English

Growing low-dimensional supramolecular crystals directly from 3D particles

Materials Science 2018-02-08 v1 Atomic and Molecular Clusters

Abstract

We show that one-dimensional (1D) nanostructures and two-dimensional (2D) supramolecular crystals of organic semiconductors can be grown on substrates under ambient conditions directly from three-dimensional (3D) organic crystals. The approach does not require dissolving, melting or evaporating of the source crystals and is based on the Organic Solid-Solid Wetting Deposition (OSWD). We exemplify our approach by the pigment quinacridone (QAC). Scanning Tunnelling Microscopy (STM) investigations show that the structures of the resulting 2D crystals are similar to the chain arrangement of the alpha and beta QAC polymorphs and are independent of the 3D source crystal polymorph (gamma). Furthermore, distinct 1D chains can be produced systematically.

Keywords

Cite

@article{arxiv.1802.02228,
  title  = {Growing low-dimensional supramolecular crystals directly from 3D particles},
  author = {Alexander Eberle and Adrian Nosek and Johannes Büttner and Thomas Markert and Frank Trixler},
  journal= {arXiv preprint arXiv:1802.02228},
  year   = {2018}
}

Comments

12 pages, 13 figures

R2 v1 2026-06-23T00:13:49.531Z