English

Giant thermoelectric power factor anisotropy in PtSb$_{1.4}$Sn$_{0.6}$

Materials Science 2022-08-30 v1 Strongly Correlated Electrons

Abstract

We report giant anisotropy in thermoelectric power factor (S2σS^2\sigma) of marcasite structure-type PtSb1.4_{1.4}Sn0.6_{0.6}. PtSb1.4_{1.4}Sn0.6_{0.6}, synthesized using ambient pressure flux growth method upon mixing Sb and Sn on the same atomic site, is a new phase different from both PtSb2_2 and PtSn2_2 that crystallize in the cubic Pa3ˉPa\bar{3} pyrite and Fm3ˉmFm\bar{3}m fluorite unit cell symmetry, respectively. Giant difference in S2σS^2\sigma for heat flow applied along different principal directions of the orthorhombic unit cell mostly stems from anisotropic Seebeck coefficients.

Keywords

Cite

@article{arxiv.2208.08647,
  title  = {Giant thermoelectric power factor anisotropy in PtSb$_{1.4}$Sn$_{0.6}$},
  author = {Yu Liu and Zhixiang Hu and Michael O. Ogunbunmi and Eli Stavitski and Klaus Attenkofer and Svilen Bobev and Cedomir Petrovic},
  journal= {arXiv preprint arXiv:2208.08647},
  year   = {2022}
}