We have performed density functional theory calculation and tight binging analysis in order to investigate the mechanism for the giant Rashba-type spin splitting (RSS) observed in Bi/Ag(111). We find that local orbital angular momentum induces momentum and spin dependent charge distribution which results in spin-dependent hopping. We show that the spin-dependent interatomic-hopping in Bi/Ag(111) works as a strong effective field and induces the giant RSS, indicating that the giant RSS is driven by hopping, not by a uniform electric field. The effective field from the hopping energy difference amounts to be ~18 V/{\AA}. This new perspective on the RSS gives us a hint for the giant RSS mechanism in general and should provide a strategy for designing new RSS materials by controlling spin-dependence of hopping energy between the neighboring atomic layers.
@article{arxiv.1709.04087,
title = {Giant Rashba-type spin splitting through spin-dependent interatomic-hopping},
author = {Jisook Hong and Jun-Won Rhim and Inkyung Song and Changyoung Kim and Seung Ryong Park and Ji Hoon Shim},
journal= {arXiv preprint arXiv:1709.04087},
year = {2020}
}