Generalized Boltzmann distributions for systems strongly coupled to large finite bath -- a microcanonical approach
Mathematical Physics
2021-08-11 v5 Statistical Mechanics
math.MP
Abstract
The theory of probability shows that, as the fraction , the conditional probability for , given , has a limit law , where equals to plus an additional term, contributed from the correlation between and bath . By applying this limit law to an isolated composite system consisting of two strongly coupled parts, a system of interest and a large but finite bath, we derive the generalized Boltzmann distribution law for the system of interest in the exponential form of a redefined Hamiltonian and corrected Boltzmann temperature that reflects the modification due to strong system-bath coupling and the large but finite bath.
Keywords
Cite
@article{arxiv.1811.11321,
title = {Generalized Boltzmann distributions for systems strongly coupled to large finite bath -- a microcanonical approach},
author = {Yu-Chen Cheng and Wenning Wang and Zhiyue Lu and Hong Qian},
journal= {arXiv preprint arXiv:1811.11321},
year = {2021}
}
Comments
Abstract revised; Minor revisions to the main text