English

Generalized Boltzmann distributions for systems strongly coupled to large finite bath -- a microcanonical approach

Mathematical Physics 2021-08-11 v5 Statistical Mechanics math.MP

Abstract

The theory of probability shows that, as the fraction Xn/Y0X_n/Y\to 0, the conditional probability for XnX_n, given Xn+Yhδ:=[h,h+δ]X_n+Y \in h_{\delta}:=[h, h+\delta], has a limit law fXn(x)eψn(hδ)xf_{X_n}(x)e^{-\psi_n(h_\delta)x}, where ψn(hδ)\psi_n(h_\delta) equals to [lnP(Yyδ)/y]y=h[\partial \ln P(Y \in y_\delta)/\partial y]_{y=h} plus an additional term, contributed from the correlation between XnX_n and bath YY. By applying this limit law to an isolated composite system consisting of two strongly coupled parts, a system of interest and a large but finite bath, we derive the generalized Boltzmann distribution law for the system of interest in the exponential form of a redefined Hamiltonian and corrected Boltzmann temperature that reflects the modification due to strong system-bath coupling and the large but finite bath.

Keywords

Cite

@article{arxiv.1811.11321,
  title  = {Generalized Boltzmann distributions for systems strongly coupled to large finite bath -- a microcanonical approach},
  author = {Yu-Chen Cheng and Wenning Wang and Zhiyue Lu and Hong Qian},
  journal= {arXiv preprint arXiv:1811.11321},
  year   = {2021}
}

Comments

Abstract revised; Minor revisions to the main text