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Gapless quantum spin liquid in the triangular system Sr$_{3}$CuSb$_{2}$O$_{9}$

Strongly Correlated Electrons 2020-12-29 v3

Abstract

We report gapless quantum spin liquid behavior in the layered triangular Sr3_{3}CuSb2_{2}O9_{9} (SCSO) system. X-ray diffraction shows superlattice reflections associated with atomic site ordering into triangular Cu planes well-separated by Sb planes. Muon spin relaxation (μ\muSR) measurements show that the S=12S = \frac{1}{2} moments at the magnetically active Cu sites remain dynamic down to 65 mK in spite of a large antiferromagnetic exchange scale evidenced by a large Curie-Weiss temperature θcw\theta_{\mathrm{cw}} \simeq -143 K as extracted from the bulk susceptibility. Specific heat measurements also show no sign of long-range order down to 0.35 K. The magnetic specific heat (C\mathit{C}m_{\mathrm{m}}) below 5 K reveals a C\mathit{C}m_{\mathrm{m}} == γT\gamma T + αT\alpha T2^{2} behavior. The significant TT2^{2} contribution to the magnetic specific heat invites a phenomenology in terms of the so-called Dirac spinon excitations with a linear dispersion. From the low-TT specific heat data, we estimate the dominant exchange scale to be \sim 36 K using a Dirac spin liquid ansatz which is not far from the values inferred from microscopic density functional theory calculations (\sim 45 K) as well as high-temperature susceptibility analysis (\sim 70 K). The linear specific heat coefficient is about 18 mJ/mol-K2^2 which is somewhat larger than for typical Fermi liquids.

Keywords

Cite

@article{arxiv.2012.01239,
  title  = {Gapless quantum spin liquid in the triangular system Sr$_{3}$CuSb$_{2}$O$_{9}$},
  author = {S. Kundu and Aga Shahee and Atasi Chakraborty and K. M. Ranjith and B. Koo and Jörg Sichelschmidt and Mark T. F. Telling and P. K. Biswas and M. Baenitz and I. Dasgupta and Sumiran Pujari and A. V. Mahajan},
  journal= {arXiv preprint arXiv:2012.01239},
  year   = {2020}
}

Comments

16 pages, 21 figures, including supplementary material. A $S = \frac{1}{2}$ Dirac spin liquid scenario has been put forward to explain the field-dependent specific heat data. Comments are welcome

R2 v1 2026-06-23T20:40:25.242Z