The valence band maxima of most group-VI transition metal dichalcogenide thin films remain at the Γ-point all the way from bulk to bilayer. In this paper we develop a continuum theory of the moir\`e minibands that are formed in the valence bands of Γ-valley homobilayers by a small relative twist. Our effective theory is benchmarked against large-scale ab initio electronic structure calculations that account for lattice relaxation. As a consequence of an emergent D6 symmetry we find that low-energy Γ-valley moir\`e holes differ qualitatively from their K-valley counterparts addressed previously; in energetic order the first three bands realize i) a single-orbital model on a honeycomb lattice, ii) a two-orbital model on a honeycomb lattice, and iii) a single-orbital model on a kagome lattice.
Cite
@article{arxiv.2008.01735,
title = {$\Gamma$-Valley Transition-Metal-Dichalcogenide Moir\`e Bands},
author = {M. Angeli and A. H. MacDonald},
journal= {arXiv preprint arXiv:2008.01735},
year = {2021}
}
Comments
We added the Supplementary Material and corrected few typos