English

From Random Determinants to the Ground State

Quantum Physics 2025-11-19 v1 Strongly Correlated Electrons Chemical Physics

Abstract

Accurate quantum many-body calculations often depend on reliable reference states or good human-designed ans\"atze, yet these sources of knowledge can become unreliable in hard problems like strongly correlated systems. We introduce the Trimmed Configuration Interaction (TrimCI) method, a prior-knowledge-free algorithm that builds accurate ground states directly from random Slater determinants. TrimCI iteratively expands the variational space and trims away unimportant states, allowing a random initial core to self-refine into an accurate approximation of exact ground state. Across challenging benchmarks, TrimCI achieves state-of-the-art accuracy with strikingly efficiency gains of several orders of magnitude. For [4Fe-4S] cluster, it matches recent quantum computing results with 10610^6-fold fewer determinants and CPU-hours. For the nitrogenase P-cluster, it matches selected-CI accuracy using 10510^5-fold fewer determinants. For 8×88\times8 Hubbard model, it recovers over 99%99\% of the ground-state energy using only 102810^{-28} of the Hilbert space. In some regimes, TrimCI attains orders-of-magnitude higher accuracy than AFQMC method. These results demonstrate that high-accuracy many-body ground states can be discovered directly from random determinants, establishing TrimCI as a prior-knowledge-free, accurate and highly efficient framework for quantum many-body systems. The compact explicit wavefunctions it produces further enable direct and rapid evaluation of observables.

Keywords

Cite

@article{arxiv.2511.14734,
  title  = {From Random Determinants to the Ground State},
  author = {Hao Zhang and Matthew Otten},
  journal= {arXiv preprint arXiv:2511.14734},
  year   = {2025}
}

Comments

13 pages, 5 figures

R2 v1 2026-07-01T07:43:52.041Z