English

Friedel oscillations and helium bubble ordering in molybdenum

Materials Science 2021-01-01 v1

Abstract

Helium ions implanted into metals can evolve into ordered bubbles isomorphic to the host lattice. Long-range elastic interaction is generally believed to drive the formation of bubble superlattice, but little is known about the thermodynamics at the very initial stage. Our first-principles calculations demonstrate that in molybdenum, Friedel oscillations induced by individual helium generate both potential barriers and wells for helium clustering at short He-He distances. Such repulsion and attraction at high concentration provide a thermodynamic diving force to assist lining up randomly distributed He atoms into ordered bubbles. Friedel oscillations might have general impact on solute-solute interactions in alloys.

Keywords

Cite

@article{arxiv.2012.15402,
  title  = {Friedel oscillations and helium bubble ordering in molybdenum},
  author = {W. T. Geng and Q. Zhan},
  journal= {arXiv preprint arXiv:2012.15402},
  year   = {2021}
}

Comments

11 pages, 4 figures

R2 v1 2026-06-23T21:37:25.875Z