In this paper for the first time we synthesized the compound BaCe0.7Nd0.2In0.1O2.85 by solid-state reaction. The phase has orthorhombic structure (space group Pmcn). We also measured the standard formation enthalpies of BaCe0.7Nd0.2In0.1O2.85 by solution calorimetry in 1 M HCl with 0.1 M KI. We determined the stability of Nd(In)-doped barium cerate with respect to mixtures of binary oxides. On the basis of these data we established that above-mentioned mixed oxide is thermodynamically stable with respect to their decomposition into binary oxides at room temperatures. We also established that BaCe0.7Nd0.2In0.1O2.85 oxide is thermodynamically favoured than BaCe0.8Nd0.2O2.9.
@article{arxiv.1212.0344,
title = {Formation enthalpy of BaCe0.7Nd0.2In0.1O2.85},
author = {M. Yu. Matskevich and N. I. Matskevich and Th. Wolf and A. N. Bryzgalova and T. I. Chupakhina and O. I. Anyfrieva and I. V. Vyazovkin},
journal= {arXiv preprint arXiv:1212.0344},
year = {2012}
}