English

Force-induced desorption of uniform branched polymers

Statistical Mechanics 2019-03-27 v4

Abstract

We analyze the phase diagrams of self-avoiding walk models of uniform branched polymers adsorbed at a surface and subject to an externally applied vertical pulling force which, at critical values, desorbs the polymer. In particular, models of adsorbed branched polymers with homeomorphism types stars, tadpoles, dumbbells and combs are examined. These models generalize earlier results on linear, ring and 33-star polymers. In the case of star polymers we confirm a phase diagram with four phases (a free, an adsorbed, a ballistic, and a mixed phase) first seen in the paper by Janse van Rensburg EJ and Whittington SG 2018 J. Phys. A: Math. Theor. 51 204001 for 33-star polymers. The phase diagram of tadpoles may include four phases (including a mixed phase) if the tadpole is pulled from the adsorbing surface by the end vertex of its tail. If it is instead pulled from the middle vertex of its head, then there are only three phases (the mixed phase is absent). For a dumbbell pulled from the middle vertex of a ring, there are only three phases. For combs with tt teeth there are four phases, independent of the value of tt for all t1t \ge 1.

Keywords

Cite

@article{arxiv.1809.06939,
  title  = {Force-induced desorption of uniform branched polymers},
  author = {EJ Janse van Rensburg and SG Whittington},
  journal= {arXiv preprint arXiv:1809.06939},
  year   = {2019}
}