English

First-principles study of two-dimensional transition metal carbide M n+1 C n O 2(M=Nb,Ta)

Superconductivity 2024-03-12 v1

Abstract

In the present work, the three stable MXenes M n+1 C n O 2 (M=Nb,Ta) are explored based onfirst-principles calculations. These materials are important derivatives of 2D materials and exhib-it distinctive properties, holding vast potential in nanodevices. All these M n+1 C n O 2 (M=Nb,Ta)materials exhibit outstanding superconducting performance, with corresponding superconductingtransition temperatures of 23.00K, 25.00K, and 29.00K. Analysis reveals that the high supercon-ducting transition temperatures of MXenes M n+1 C n O 2 (M=Nb,Ta) are closely associated with thehigh value of the logarithmic average of phonon frequencies, {\omega} log , and the strong electron-phononcoupling (EPC), attributed to the crucial contribution of low-frequency phonons. Additionally, weapplied strain treatments of 2% and 4% to M n+1 C n O 2 (M=Nb,Ta), resulting in varying changes insuperconducting transition temperatures under different strains.

Keywords

Cite

@article{arxiv.2403.06380,
  title  = {First-principles study of two-dimensional transition metal carbide M n+1 C n O 2(M=Nb,Ta)},
  author = {Yue Shang and Yifan Han and Wenhui Wan and Yong Liu and Yanfeng Ge},
  journal= {arXiv preprint arXiv:2403.06380},
  year   = {2024}
}