English

Finite-time effects on a first-order irreversible phase transition

Statistical Mechanics 2026-01-01 v1

Abstract

The first-order irreversible phase transition (FOIPT) of the ZGB model [Ziff, Gulari, Barshad, Phys. Rev. Lett. \textbf{56} (1986) 2553] for the catalytic oxidation of carbon monoxide is studied numerically in the presence of a slowly time-dependent, spatially uniform carbon monoxide pressure, with standard constant pressure simulations. This method allows us to observe finite-time effects close to the FOIPT, as well as evidence that a dynamic phase transition occurs. The location of this transition is measured very precisely and compared with previous results in the literature.

Keywords

Cite

@article{arxiv.2512.23833,
  title  = {Finite-time effects on a first-order irreversible phase transition},
  author = {Ernesto S. Loscar},
  journal= {arXiv preprint arXiv:2512.23833},
  year   = {2026}
}

Comments

26 pages, 9 figures

R2 v1 2026-07-01T08:45:00.690Z