English

Finite-size effects in the diffusion dynamics of a glass-forming binary mixture with large size ratio

Soft Condensed Matter 2023-03-10 v1

Abstract

Extensive molecular dynamics (MD) computer simulations of an equimolar glass-forming AB mixture with large size ratio are presented. While the large A particles show a glass transition around the critical density of mode coupling theory ρc\rho_c, the small B particles remain mobile with a relatively weak decrease of their self diffusion coefficient DBD_{\rm B} with increasing density. Surprisingly, around ρc\rho_c, the self-diffusion coefficient of the A particles, DAD_{\rm A}, also starts to follow a rather weak dependence on density. We show that this is due to finite-size effects that can be understood from the analysis of the collective interdiffusion dynamics.

Keywords

Cite

@article{arxiv.2202.12189,
  title  = {Finite-size effects in the diffusion dynamics of a glass-forming binary mixture with large size ratio},
  author = {Vinay Vaibhav and Jürgen Horbach and Pinaki Chaudhuri},
  journal= {arXiv preprint arXiv:2202.12189},
  year   = {2023}
}

Comments

10 pages, 8 figures