Finite-size effects in the diffusion dynamics of a glass-forming binary mixture with large size ratio
Soft Condensed Matter
2023-03-10 v1
Abstract
Extensive molecular dynamics (MD) computer simulations of an equimolar glass-forming AB mixture with large size ratio are presented. While the large A particles show a glass transition around the critical density of mode coupling theory , the small B particles remain mobile with a relatively weak decrease of their self diffusion coefficient with increasing density. Surprisingly, around , the self-diffusion coefficient of the A particles, , also starts to follow a rather weak dependence on density. We show that this is due to finite-size effects that can be understood from the analysis of the collective interdiffusion dynamics.
Keywords
Cite
@article{arxiv.2202.12189,
title = {Finite-size effects in the diffusion dynamics of a glass-forming binary mixture with large size ratio},
author = {Vinay Vaibhav and Jürgen Horbach and Pinaki Chaudhuri},
journal= {arXiv preprint arXiv:2202.12189},
year = {2023}
}
Comments
10 pages, 8 figures