English

Field-theoretical approach to a dense polymer with an ideal binary mixture of clustering centers

Materials Science 2015-05-28 v1 Soft Condensed Matter

Abstract

We propose a field-theoretical approach to a polymer system immersed in an ideal mixture of clustering centers. The system contains several species of these clustering centers with different functionality, each of which connects a fixed number segments of the chain to each other. The field-theory is solved using the saddle point approximation and evaluated for dense polymer melts using the Random Phase Approximation. We find a short-ranged effective inter-segment interaction with strength dependent on the average segment density and discuss the structure factor within this approximation. We also determine the fractions of linkers of the different functionalities.

Keywords

Cite

@article{arxiv.1106.6076,
  title  = {Field-theoretical approach to a dense polymer with an ideal binary mixture of clustering centers},
  author = {Riccardo Fantoni and Kristian K. Muller-Nedebock},
  journal= {arXiv preprint arXiv:1106.6076},
  year   = {2015}
}

Comments

27 pages, 9 figures, accepted on Phys. Rev. E