In the series La_{2/3-x}Tb_{x}Ca_{1/3}MnO_{3}, it is known that the compositions are ferromagnetic for smaller values of x and show spin glass characteristics at larger values of x. Our studies on the magnetic properties of various compositions in the La_{2/3-x}Tb_{x}Ca_{1/3}MnO_{3} series show that the cross over from ferromagnetic to spin glass region takes place above x ~ 1/8. Also, a low temperature anomaly at 30 K, observed in the ac susceptibility curves, disappears for compositions above this critical value of x. A mixed phase region coexists in the narrow compositional range 0.1 <= x <= 0.125, indicating that the ferromagnetic to spin glass cross over is not abrupt.
@article{arxiv.0802.4009,
title = {Ferromagnetic to spin glass cross over in (La,Tb)_{2/3}Ca_{1/3}MnO_{3}},
author = {C. Raj Sankar and S. Vijayanand and P. A. Joy},
journal= {arXiv preprint arXiv:0802.4009},
year = {2009}
}