Faster uphill relaxation in thermodynamically equidistant temperature quenches
Abstract
We uncover an unforeseen asymmetry in relaxation -- for a pair of thermodynamically equidistant temperature quenches, one from a lower and the other from a higher temperature, the relaxation at the ambient temperature is faster in case of the former. We demonstrate this finding on hand of two exactly solvable many-body systems relevant in the context of single-molecule and tracer-particle dynamics. We prove that near stable minima and for all quadratic energy landscapes it is a general phenomenon that also exists in a class of non-Markovian observables probed in single-molecule and particle-tracking experiments. The asymmetry is a general feature of reversible overdamped diffusive systems with smooth single-well potentials and occurs in multi-well landscapes when quenches disturb predominantly intra-well equilibria. Our findings may be relevant for the optimization of stochastic heat engines.
Cite
@article{arxiv.2002.08237,
title = {Faster uphill relaxation in thermodynamically equidistant temperature quenches},
author = {Alessio Lapolla and Aljaž Godec},
journal= {arXiv preprint arXiv:2002.08237},
year = {2022}
}
Comments
Contains an Erratum with corrected Proof of Theorem 1 (see https://doi.org/10.1103/PhysRevLett.128.229901) and a couple of typos in the Supplementary Material were corrected