English

Failure of the random phase approximation correlation energy

Other Condensed Matter 2009-03-26 v1 Strongly Correlated Electrons

Abstract

The random phase approximation (RPA) to the correlation energy is extended to fractional occupations and its performance examined for exact conditions on fractional charges and fractional spins. RPA satisfies the constancy condition for fractional spins that leads to correct bond dissociation and no static correlation error for H2_2 but massively fails for fractional charges, with an enormous delocalization error even for a one-electron system such as H2+_2^+. Other methods such as range-separated RPA can reduce this delocalization error but only at the cost of increasing the static correlation error. None of the RPA methods seem to have the discontinuous nature required to satisfy both exact conditions and the full unified condition, emphasizing the need to go further than just smooth functionals of the orbitals.

Keywords

Cite

@article{arxiv.0903.4403,
  title  = {Failure of the random phase approximation correlation energy},
  author = {Paula Mori-Sánchez and Aron J. Cohen and Weitao Yang},
  journal= {arXiv preprint arXiv:0903.4403},
  year   = {2009}
}

Comments

4 pages, 7 figures

R2 v1 2026-06-21T12:44:29.054Z