English

Excitons in single-walled carbon nanotubes: environmental effect

Materials Science 2010-12-15 v2

Abstract

The properties of excitons in semiconducting single-walled carbon nanotubes (SWCNTs), isolated in vacuum or a medium, and their contributions to the optical spectra of nanotubes are studied within the elementary potential model, in which an exciton is represented as a bound state of two oppositely charged quasi-particles confined to the nanotube surface. The emphasis is given on the influence of dielectric environment surrounding a nanotube on the exciton spectra. For nanotubes in environment with permittivity less than 1.8 the ground-state exciton binding energies exceed the respective energy gaps, while the obtained binding energies of excitons in nanotubes in a medium with permittivity greater than 4 are in good accordance with the corresponding experimental data and consistent with known scaling relation for the environmental effect. The stabilization process of single-electron spectrum in SWCNTs in media with rather low permittivities is discussed.

Keywords

Cite

@article{arxiv.0901.0093,
  title  = {Excitons in single-walled carbon nanotubes: environmental effect},
  author = {Oleksii A. Smyrnov},
  journal= {arXiv preprint arXiv:0901.0093},
  year   = {2010}
}

Comments

8 pages, 4 figures, 2 tables

R2 v1 2026-06-21T11:56:53.308Z