English

Exchange interaction and correlations radically change behaviour of a quantum particle in a classically forbidden region

Quantum Physics 2015-05-13 v2

Abstract

Exchange interaction strongly influences the long-range behaviour of localised electron orbitals and quantum tunneling amplitudes. It violates the oscillation theorem (creates extra nodes) and produces a power-law decay instead of the usual exponential decrease at large distances. For inner orbitals inside molecules decay is r2r^{-2}, for macroscopic systems cos(kfr)rν\cos{(k_f r)} r^{-\nu}, where kfk_f is the Fermi momentum and ν=3\nu=3 for 1D, ν=\nu=3.5 for 2D and ν=\nu=4 for 3D crystal. Correlation corrections do not change these conclusions. Slow decay increases the exchange interaction between localized spins and the under-barrier tunneling amplitude. The under-barrier transmission coefficients in solids (e.g. for point contacts) become temperature-dependent.

Keywords

Cite

@article{arxiv.0809.2847,
  title  = {Exchange interaction and correlations radically change behaviour of a quantum particle in a classically forbidden region},
  author = {V. V. Flambaum},
  journal= {arXiv preprint arXiv:0809.2847},
  year   = {2015}
}
R2 v1 2026-06-21T11:20:58.096Z