Exchange interaction and correlations radically change behaviour of a quantum particle in a classically forbidden region
Quantum Physics
2015-05-13 v2
Abstract
Exchange interaction strongly influences the long-range behaviour of localised electron orbitals and quantum tunneling amplitudes. It violates the oscillation theorem (creates extra nodes) and produces a power-law decay instead of the usual exponential decrease at large distances. For inner orbitals inside molecules decay is , for macroscopic systems , where is the Fermi momentum and for 1D, 3.5 for 2D and 4 for 3D crystal. Correlation corrections do not change these conclusions. Slow decay increases the exchange interaction between localized spins and the under-barrier tunneling amplitude. The under-barrier transmission coefficients in solids (e.g. for point contacts) become temperature-dependent.
Cite
@article{arxiv.0809.2847,
title = {Exchange interaction and correlations radically change behaviour of a quantum particle in a classically forbidden region},
author = {V. V. Flambaum},
journal= {arXiv preprint arXiv:0809.2847},
year = {2015}
}