English

Exact Solution of Two-Species Ballistic Annihilation with General Pair-Reaction Probability

Statistical Mechanics 2016-08-31 v2

Abstract

The reaction process A+B>CA+B->C is modelled for ballistic reactants on an infinite line with particle velocities vA=cv_A=c and vB=cv_B=-c and initially segregated conditions, i.e. all A particles to the left and all B particles to the right of the origin. Previous, models of ballistic annihilation have particles that always react on contact, i.e. pair-reaction probability p=1p=1. The evolution of such systems are wholly determined by the initial distribution of particles and therefore do not have a stochastic dynamics. However, in this paper the generalisation is made to p<1p<1, allowing particles to pass through each other without necessarily reacting. In this way, the A and B particle domains overlap to form a fluctuating, finite-sized reaction zone where the product C is created. Fluctuations are also included in the currents of A and B particles entering the overlap region, thereby inducing a stochastic motion of the reaction zone as a whole. These two types of fluctuations, in the reactions and particle currents, are characterised by the `intrinsic reaction rate', seen in a single system, and the `extrinsic reaction rate', seen in an average over many systems. The intrinsic and extrinsic behaviours are examined and compared to the case of isotropically diffusing reactants.

Keywords

Cite

@article{arxiv.cond-mat/9705042,
  title  = {Exact Solution of Two-Species Ballistic Annihilation with General Pair-Reaction Probability},
  author = {M. J. E. Richardson},
  journal= {arXiv preprint arXiv:cond-mat/9705042},
  year   = {2016}
}

Comments

22 pages, 2 figures, typos corrected