English

Equivalence of residual entropy of hexagonal and cubic ices from tensor network methods

Statistical Mechanics 2025-12-01 v1

Abstract

The long-standing question of whether the residual entropy of hexagonal ice (ShS_h) equals that of cubic ice (ScS_c) remains unresolved despite decades of research on ice-type models. While analytical studies have established the inequality ShScS_h \geq S_c, numerical investigations suggest that the two values are very close. In this work, we revisit this problem using high-precision tensor-network methods. In Monte Carlo approaches the residual entropy cannot be directly obtained by sampling the ground-state degeneracy space, however, the tensor-network framework enables an explicit encoding of the "ice rule'' into local tensors, and then the residual entropy is transformed into finding the largest eigenvalue of a transfer operator in the form of a projected entangled-pair operator, which allows high-accuracy numerical evaluation. Meanwhile, we propose a new perspective based on analyzing the normality of the transfer operator, and demonstrate that if the operator is normal, the equality Sh=ScS_h = S_c follows directly. Then the variational tensor network methods are employed to numerically verify this normality. Finally both residual entropies are directly computed by using our recently developed split corner transfer matrix renormalization group algorithm, providing a rigorous evidence supporting the equality between ShS_h and ScS_c.

Keywords

Cite

@article{arxiv.2511.22477,
  title  = {Equivalence of residual entropy of hexagonal and cubic ices from tensor network methods},
  author = {Xia-Ze Xu and Tong-Yu Lin and Guang-Ming Zhang},
  journal= {arXiv preprint arXiv:2511.22477},
  year   = {2025}
}

Comments

10 pages, 6 figures, two tables