We studied optical absorption of single-walled carbon nanotubes by varying the dielectric environment. For the two different components of the broad UV absorption feature conventionally referred to as the pi-plasmon, we find that the component at 5.0 - 5.3 eV exhibits remarkable spectral changes, based on which we attribute this to a dipolar radial surface plasmon. However, the component at ~4.5 eV remains unchanged, raising a fundamental question as to its conventional attribution. We discuss its relation with the absorption feature at ~4.5 eV in graphite arising from an interband transition.
@article{arxiv.0811.4692,
title = {Environmental Effect on the UV Optical Absorption of Single-Walled Carbon Nanotubes},
author = {Yoichi Murakami and Shigeo Maruyama},
journal= {arXiv preprint arXiv:0811.4692},
year = {2009}
}