Energy barriers, entropy barriers, and non-Arrhenius behavior in a minimal glassy model
Abstract
We study glassy dynamics using a simulation of three soft Brownian particles confined to a two-dimensional circular region. If the circular region is large, the disks freely rearrange, but rearrangements are rarer for smaller system sizes. We directly measure a one-dimensional free energy landscape characterizing the dynamics. This landscape has two local minima corresponding to the two distinct disk configurations, separated by a free energy barrier which governs the rearrangement rate. We study several different interaction potentials and demonstrate that the free energy barrier is composed of a potential energy barrier and an entropic barrier. The heights of both of these barriers depend on temperature and system size, demonstrating how non-Arrhenius behavior can arise close to the glass transition.
Keywords
Cite
@article{arxiv.1511.09453,
title = {Energy barriers, entropy barriers, and non-Arrhenius behavior in a minimal glassy model},
author = {Xin Du and Eric R. Weeks},
journal= {arXiv preprint arXiv:1511.09453},
year = {2016}
}
Comments
9 pages, 10 figures