Endohedral Impurities in Carbon Nanotubes
Materials Science
2007-05-23 v1
Abstract
A generalization of the Anderson model that includes pseudo-Jahn-Teller impurity coupling is proposed to describe distortions of an endohedral impurity in a carbon nanotube. Treating the distortion within mean-field theory, spontaneous axial symmetry breaking is found when the vibronic coupling strength g exceeds a critical value g. The effective potential in the symmetry-broken state is found to have O(2) symmetry, in agreement with numerical calculations. For metallic zigzag nanotubes endohedrally-doped with transition metals in the dilute limit, the low-energy properties of the system may display two-channel Kondo behavior; however, strong vibronic coupling is seen to exponentially suppress the Kondo energy scale.
Keywords
Cite
@article{arxiv.cond-mat/0212269,
title = {Endohedral Impurities in Carbon Nanotubes},
author = {Dennis P. Clougherty},
journal= {arXiv preprint arXiv:cond-mat/0212269},
year = {2007}
}
Comments
4 pages, 2 figures