Embedded metal cluster in strong laser fields
Abstract
We discuss microscopic mechanisms of the violent dynamics following strong laser excitation of a metal cluster embedded in a rare gas matrix, taking as test case Na@Ar. This covers at least two aspects : first, it represents the typical experimental situation of metal clusters handled in raregas matrices or a finite drop of surrounding raregas material, and second, it serves as a generic test case for highly excited chromophores in inert surroundings addressing questions of energy transport and perturbation of the medium. We simulate the process up to 10 ps using a mixed quantum mechanical (for the electrons) and classical (ions and atoms) approach and analyze the emerging dynamics with respect to all basic constituents : cluster electrons, cluster ions, and matrix atoms. We find several stages of relaxation taking place with time scales from a few fs to over a few ps and much slower processes remaining for long after the simulation. A particularly interesting aspect is that the surrounding raregas material stabilizes a highly charged metal cluster which would otherwise explode without delay.
Cite
@article{arxiv.0707.1442,
title = {Embedded metal cluster in strong laser fields},
author = {F. Fehrer and P. M. Dinh and P. -G. Reinhard and E. Suraud},
journal= {arXiv preprint arXiv:0707.1442},
year = {2008}
}
Comments
13 pages, 4 figures, Comp. Mat. Sci. (in press)