English

Electrophoresis simulated with the cage model for reptation

Statistical Mechanics 2007-05-23 v1

Abstract

The cage model for polymer reptation is extended to simulate DC electrophoresis. The drift velocity v of a polymer with length L in an electric field with strength E shows three different regions: if the strength of field is small, the drift velocity scales as E/L; for slightly larger strengths, it scales as E^2, independent of length; for high fields, but still E much smaller than 1, the drift velocity decreases exponentially to zero. The behaviour of the first two regions are in agreement with earlier reports on simulations of the Duke-Rubinstein model and with experimental work on DNA polymers in agarose gel.

Keywords

Cite

@article{arxiv.cond-mat/9906090,
  title  = {Electrophoresis simulated with the cage model for reptation},
  author = {H. R. W. Beljaars and A. van Heukelum},
  journal= {arXiv preprint arXiv:cond-mat/9906090},
  year   = {2007}
}

Comments

14 pages, 9 pictures, 2 tables