We present electronic structure calculations together with resistivity, susceptibility, and specific heat measurements for TaB2 to search for the recently contradictorily reported superconductivity and to study related normal state properties. We ascribe the absence of superconductivity down to 1.5 K for our TaB2 samples to the generally weak electron phonon coupling derived from comparison of the calculated and measured specific heat constants. For the E2g and the B1gΓ point phonons we derive from the calculated deformation potentials very small electron phonon couplings for these modes, opposite to the strong coupling of the E2g mode in MgB2, probably responsible for its high Tc. In comparison to MgB2, we discuss the origin of the quite different features in the density of states and of the Fermi surfaces. The differences are mainly due to the strong hybridization between Ta 5d and B 2p states outside the hexagonal basis plane.
@article{arxiv.cond-mat/0106092,
title = {Electronic structure and weak electron-phonon coupling in TaB$_2$},
author = {H. Rosner and W. E. Pickett and S. -L. Drechsler and A. Handstein and G. Behr and G. Fuchs and K. Nenkov and K. -H. Müller and H. Eschrig},
journal= {arXiv preprint arXiv:cond-mat/0106092},
year = {2009}
}