Electron transfer under the Floquet modulation in donor-bridge-acceptor systems
Chemical Physics
2022-08-12 v1
Abstract
Electron transfer (ET) processes are of broad interest in modern chemistry. With the advancements of experimental techniques, one may modulate the ET via such as the light-matter interactions. In this work, we study the ET under a Floquet modulation occurring in the donor-bridge-acceptor systems, with the rate kernels projected out from the exact disspaton equation of motion formalism. This together with the Floquet theorem enables us to investigate the interplay between the intrinsic non-Markovianity and the driving periodicity. The observed rate kernel exhibits a Herzberg-Teller-like mechanism induced by the bridge fluctuation subject to effective modulation.
Cite
@article{arxiv.2203.11558,
title = {Electron transfer under the Floquet modulation in donor-bridge-acceptor systems},
author = {Yu Su and Zi-Hao Chen and Haojie Zhu and Yao Wang and Lu Han and Rui-Xue Xu and YiJing Yan},
journal= {arXiv preprint arXiv:2203.11558},
year = {2022}
}
Comments
10 pages, 6 figures