Electron-nucleus Araki-Sucher correction in the hydrogen molecule isotopologues
Abstract
The quantum electrodynamic Araki-Sucher correction arising from the interaction between electrons and nuclei is calculated for rovibrational energy levels of the hydrogen molecule and its isotopologues. The corresponding expectation value is evaluated across a wide range of internuclear distances using the Born-Oppenheimer approximation. The electronic wave function is represented as a linear combination of explicitly correlated Gaussian basis functions. This correction contributes approximately tenths of a megahertz (about cm) to the dissociation energy of rovibrational levels and to the transitions between them. Given recent spectroscopic measurements with an accuracy of 10 kHz, this correction is necessary to achieve sub-MHz agreement between theory and experiment.
Keywords
Cite
@article{arxiv.2511.07053,
title = {Electron-nucleus Araki-Sucher correction in the hydrogen molecule isotopologues},
author = {Jacek Komasa},
journal= {arXiv preprint arXiv:2511.07053},
year = {2025}
}
Comments
Corrected typos