English

Electric-field-driven resistive transition in multiferroic SrCo$_2$Fe$_{16}$O$_{27}$/Sr$_3$Co$_2$Fe$_{24}$O$_{41}$composite

Strongly Correlated Electrons 2022-07-11 v1 Materials Science

Abstract

We report observation of electric-field-driven resistive transition at a characteristic threshold field Eth(T)E_{th}(T) across a temperature range 10-200 K in an off-stoichiometric composite of (~80 vol%) W- and (~20 vol%) Z-type hexaferrites. The dielectric constant ϵ\epsilon and the relaxation time constant τ\tau too exhibit anomalous jump at Eth(T)E_{th}(T). The Eth(T)E_{th}(T), the extent of jump in resistivity (Δρ\Delta\rho), and the hysteresis associated with the jump [ΔEth(T)\Delta E_{th}(T)] are found to decrease systematically with the increase in temperature (TT). Several temperature-driven phase transitions have also been noticed in low and high resistive states (LRS and HRS). The temperature-driven conduction turns out to be governed by activated hopping of small polarons at all the phases with electric (EE) and magnetic (HH) field dependent activation energy U(E,H)U(E,H). Interestingly, as the temperature is raised, the EE-driven conduction at a fixed temperature evolves from Ohmic\textit{Ohmic} to non-Ohmic\textit{non-Ohmic} across 10-200 K and within 110-200 K, ρ\rho follows three-dimensional variable range hopping (3D-VRH) with stretched exponential \sim exp[(E0/E)4]exp[(E_0/E)^4] or power law \sim (E0/E)m(E_0/E)^m (mm varies within \sim0.6-0.7 and \sim0.6-0.8 at LRS and HRS, respectively) dependence depending on the localization length (ζE\zeta_E) to diffusion length (dEd_E) ratio associated with EE-driven conduction. The ρ(E,T)\rho(E,T) follows universal scaling only at LRS within 10-110 K but not at higher temperature or at HRS. The entire set of observations has been discussed within the framework of structural evolution of the point-defect (cation vacancies or oxygen excess) network. This comprehensive map of esoteric ρETH\rho-E-T-H and ϵETH\epsilon-E-T-H patterns provides insights on defect driven effects in a composite useful for tuning both the resistive transition and multiferroicity.

Keywords

Cite

@article{arxiv.2112.06246,
  title  = {Electric-field-driven resistive transition in multiferroic SrCo$_2$Fe$_{16}$O$_{27}$/Sr$_3$Co$_2$Fe$_{24}$O$_{41}$composite},
  author = {Shubhankar Mishra and Chandan K. Ghosh and Aditi Sahoo and Dipten Bhattacharya and Suchandal Mondal and P. Mandal},
  journal= {arXiv preprint arXiv:2112.06246},
  year   = {2022}
}

Comments

12 pages, 9 figures